WebCAN = ppy dfppy pa NH2 NAN NEN bpy-A bpy-T E12(Ir"/Ir") E1/2(N^NNAN) Complex Emission vs. SCE vs. SCE [Ir(dfppy)2(bpy-A)] (1) 522 nm + 1.57 V -1.40 V [Ir(ppy)2(bpy-A)] (2) 576 nm +1.25 V -1.45 V [Ir(ppy)2(bpy-T)] (3) 583 nm + 1.24 V - 1.36 V [Ir(pq)2(bpy-T)] (4) 554 nm + 1.27 V - 1.38 V Rationalize the experimental findings and suggest the ...
Ir(ppy)3, Tris[2-phenylpyridine]iridium 94928-86-6 Ossila
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Crystals Free Full-Text Synthesis and Crystal Structure of Bis(2 ...
WebMar 24, 2024 · A new bis cyclometallated Ir (III) phosphor, [Ir (ppy) 2 L]PF 6 (ppy = 2-phenylpyridine, L = 4,4′-bis (4-fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine was prepared and structurally characterized in the solid state (X-ray diffraction) and solution (1 and 2D NMR spectroscopy). The compound exhibited yellow photoluminescence (λ em = 562 nm). WebApr 19, 2010 · The synthesis, structural characterization, electrochemistry, and molecular photophysics of [Ir(ppy)(2)(bpy-C[triple bond]C-Bodipy)](PF(6)), where ppy is 2 … WebThe reactions of monocationic Pt(II) complexes bearing N^C chelate ligands and Me2pzH, [Pt(N^C)(Me2pzH)2]PF6 (N^C = 2-phenylpyridinate (ppy−), 2-(2,4-difluorophenyl)pyridinate (dfppy−), benzo[h]quinolinate (bzq−); Me2pzH = 3,5-dimethylpyrazole), with Ag(I) ions gave Z (or U)-shaped neutral tetranuclear Pt2Ag2 complexes [Pt2Ag2(N^C)2(Me2pz)4], while … hilliard 3/4 clutch